Optical spectroscopy of ancient paper and textiles

Ancient paper and textiles represent a striking example of optically inhomogenous materials whose optical responses are strongly governed by scattering effects. In order to recover the absorption coefficient from non-invasive and nondestructive reflectance measurements a specific approach based on Kubelka-Munk two-flux theory must be applied. In this way quantitative chemical information, such as chromophores concentration, can be obtained, as well as quantitative spectra of additional substances such as pigments or dyes. Results on a folio of the Codex on the Flight of Birds by Leonardo da Vinci and a linen cloth dated back to 1653 and called the Shroud of Arquata, a copy of the Shroud of Turin, will be presented

Non-Gaussian two-mode squeezing and continuous variable entanglement of linearly and circularly polarized light beams interacting with cold atoms

We investigate how entangled coherent states and superpositions of low intensity coherent states of non-Gaussian nature can be generated via non-resonant interaction between either two linearly or circularly polarized field modes and an ensemble of X-like four-level atoms placed in an optical cavity. We compare our results to recent experimental observations and argue that the non-Gaussian structure of the field states may be present in those systems.Comment: 10 pages, 7 figures, replaced with final published versio

New insight into hydration and aging mechanisms of paper by the line shape analysis of proton NMR spectra

The action of water within biological systems is strictly linked either with their physical chemical properties and with their functions. Cellulose is one of the most studied biopolymers due to its biological importance and its wide use in manufactured products. Among them, paper is mainly constituted by an almost equimolar ratio of cellulose and water. Therefore the study of the behavior of water within pristine and aged paper samples can help to shed light on the degradation mechanisms that irremediably act over time and spoil paper. In this work we present Nuclear Magnetic Resonance (NMR) experiments on modern paper samples made of pure cellulose not aged and artificially aged as well as on ancient paper samples made in 1413 in Perpignan (France). The line shape parameters of the proton NMR spectra were studied as a function of the hydration content. Results indicate that water in aged samples is progressively involved in the hydration of the byproducts of cellulose degradation. This enhances the degradation process itself through the progressive consumption of the cellulose amorphous regions

Dielectric permittivity of aqueous solutions of electrolytes probed by THz time-domain and FTIR spectroscopy

We have measured the dielectric permittivity of pure water and aqueous chlorides solutions in the range 0.2-1.5THz. We considered the relaxation spectral function as the weighted sum of two independent single-parameter Debye functions. Such an approach allowed to drastically reduce the number of the parameters used in the fit which we set only by physical considerations. The resulting functions allow to fit the experimental data for pure water and solutions of LiCl, KCl, NaCl, and CsCl and to predict the excess response on the high frequency side of the relaxation without “ad hoc” corrective terms

A weldability study of AL-CU-LI 2198 alloy

Al-Cu-Li alloys, conceived for automotive and aeronautic applications thanks to the high mechanical resistance/density ratio, exhibit weldability issues common to all light alloys. In this paper, the weldability of Al-Cu-Li 2198 alloy was studied by comparing features of welds carried out by two processes, the traditional arc welding and the friction stir welding (FSW). Welded joints were submitted to optical and SEM metallographic examinations with EDS microanalysis measurements. Mechanical characteristics were evaluated through microhardness tests and the instrumented indentation test FIMEC (Flat-top cylinder Indenter for MEchanical Characterization)

Effect of X-ray and artificial aging on parchment

In this study, the employment of the X-ray irradiation as bioremediation method to treat parchment has been deeply investigated. In particular, the effect of the irradiation doses on the structural stability of collagen, the main constituent of parchment, has been evaluated on a series of modern parchment samples by means of different opto-thermal and spectroscopic techniques in order to obtain the dose-dependent effect of irradiation on collagen. Moreover, the long-term behavior of the irradiated parchment has been considered by analyzing the same series of samples after being hygrothermally artificially aged. Characterizations by light transmission analysis, Fourier transform infrared spectroscopy and the ultraviolet-visible-near infrared (UV-Vis-NIR) reflectance one have been performed for the identification of the radio-induced effect on the parchment structure even in a dose range much wider than the need for sterilization. The obtained results have proved the safeness of the method in the short and long term confirming the applicability of this emerging procedure

Unconditional Bell-type state generation for spatially separate trapped ions

We propose a scheme for generation of maximally entangled states involving internal electronic degrees of freedom of two distant trapped ions, each of them located in a cavity. This is achieved by using a single flying atom to distribute entanglement. For certain specific interaction times, the proposed scheme leads to the non-probabilistic generation of a perfect Bell-type state. At the end of the protocol, the flying atom completely disentangles from the rest of the system, leaving both ions in a Bell-type state. Moreover, the scheme is insensitive to the cavity field state and cavity losses. We also address the situation in which dephasing and dissipation must be taken into account for the flying atom on its way from one cavity to the other, and discuss the applicability of the resulting noisy channel for performing quantum teleportation.Comment: 5 pages, 1 figure, detailed comments on the practical implementation of the scheme is added to replaced version, minor typos fixed, added references with comment

Role of cellulose oxidation in the yellowing of ancient paper

The yellowing of paper on aging causes major aesthetic damages of cultural heritage. It is due to cellulose oxidation, a complex process with many possible products still to be clarified. By comparing ultraviolet-visible reflectance spectra of ancient and artificially aged modern papers with ab initio time-dependent density functional theory calculations, we identify and estimate the abundance of oxidized functional groups acting as chromophores and responsible of paper yellowing. This knowledge can be used to set up strategies and selective chemical treatments preventing paper yellowing

Optical response of strongly absorbing inhomogeneous materials: Application to paper degradation

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Effects of microalloying on an innovative quenched and tempered plastic mold steel

presentazione orale al TMS 2008 Annual Meeting & Exhibition (TMS2008), New Orleans, LA, USA, 9/3/2008 - 13/3/200